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The preparation and applications of bio-inspired slippery surface by femtosecond laser micro-nano manufacturing
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摘要
仿猪笼草的超滑表面由于可以抵抗多种液体的粘附，具有优异的稳定性与自修复性，受到越来越广泛的关注。而飞秒激光由于其对加工材料的普适性、高精度，以及高可控性，成为仿生超滑表面制备的有力手段。本文以仿猪笼草的超滑表面为背景，以飞秒激光微加工技术为手段。从超滑表面的飞秒激光微纳制备和应用两个方面，概述了超滑表面的微纳制造和应用。针对不同材料，通过对飞秒激光进行调控，实现了在聚合物、硬脆透明材料，以及金属上的超滑表面制备。制备的超滑表面可应用于液滴、气泡操控、生物抗凝、防污和防腐等领域。最后总结超滑表面所面临的挑战。
Abstract
The slippery surface inspired by Nepenthes has received research and industry attentions due to its excellent liquid repellency, stability and self-repair property. The femtosecond laser is a powerful method to prepare the slippery surfaces due to its universality in processing materials with high precision, and high controllability. In this paper, taking the lyophobicity of slippery surfaces as a background, using femtosecond laser mico/nano-manufacturing technology as a method, the development of slippery surfaces by femtosecond laser was summarized from two perspectives, including the femtosecond laser mico/nano-manufacturing and applications of slippery surfaces. By controlling the processing parameters of femtosecond laser, the slippery surfaces could be fabricated on various materials, such as polymers, hard brittle transparent material, and metals. The prepared slippery surface can be applied in the fields of droplet and bubble manipulation, biological anticoagulation, antifouling, and anti-corrosion. Finally, the challenges of slippery surfaces were summarized.
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Key words:
- slippery surface /
- femtosecond laser /
- micro-nano manufacture /
- hemocompatibility /
- lyophobicity
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Overview
Overview: Nepenthes pitcher plant is a tropical insectivorous plant which is able to trap and digest insects. This unique property is mainly due to the rich micro/nano porous structures on the surfaces filled with a layer of lubricating, thus forming a slippery liquid-infused porous surface (SLIPS). When the insects stand on the mouth of pitch plant, they can easily fall into the pitcher because its inner surface is too smooth and thus digested by the digestive juices. Due to the mechanism of liquid-liquid contact between the lubricant and repelled object, SLIPS shows high stability and versatile liquid-repellency compared with superhydrophobic surfaces inspired by lotus leaves. Due to the fluidity of the lubricant, it can timely flow to the surface defects caused by external force and help recover the favorable slippery property. These excellent liquid repellency, stability and self-healing properties of SLIPS have attracted wide attentions from researchers, who carried out a large number of related studies. Methods to prepare SLIPS are mostly based on the three parts: fabrication of micro/nano-structures, low surface energy treatment and lubricant infusion. The fabrication of rough structure is the essential part during the process. Femtosecond laser has the ultra-short pulse width and ultra-high peak power, so it can process the majority of materials with high processing accuracy and strong controllability. Therefore, femtosecond laser has become a powerful tool for preparing the micro/nano-structure on the SLIPS. In addition, the femtosecond laser processing is directly performed on the material for subtractive manufacturing. It shows more stability compared with chemical treatment. In this paper, we focus on the preparation of SLIPS on different materials by femtosecond laser, including polymers, hard and brittle transparent materials, and metals. Then, the application of SLIPS is summarized in the fields of droplet bubble manipulation, biological anticoagulation, anti-fouling, and corrosion prevention. Finally, challenges of slippery surfaces were summarized.
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图 1 猪笼草的表面结构及其超滑性能。
Figure 1. The surface structure and slippery property of Nepenthes.
图 2 飞秒激光在各种材料表面的微纳加工。
Figure 2. The micro-nano manufacturing of femtosecond laser on all kinds of materials.
图 4 飞秒激光在微纳加工领域的高可控性。
Figure 4. The high controllability of femtosecond laser on micro-nano manufacturing field.
图 6 图案化的超滑表面以及各向异性超滑表面。
Figure 6. The patterned slippery surface and anisotropic slippery surface.
图 8 飞秒激光在金属上的超滑表面制备。
Figure 8. The slippery surface fabricated by femtosecond laser on metal.
图 10 超滑表面在液滴操控方面的应用。
Figure 10. Applications of slippery surface in droplet manipulation.
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