面向体全息存储技术的光致聚合物材料研究进展

菅佳玲, 曹琳, 魏夕桥, 等. 面向体全息存储技术的光致聚合物材料研究进展[J]. 光电工程, 2019, 46(3): 180552. doi: 10.12086/oee.2019.180552
引用本文: 菅佳玲, 曹琳, 魏夕桥, 等. 面向体全息存储技术的光致聚合物材料研究进展[J]. 光电工程, 2019, 46(3): 180552. doi: 10.12086/oee.2019.180552
Jian Jialing, Cao Lin, Wei Xiqiao, et al. A review of photopolymers on holography volume data storage[J]. Opto-Electronic Engineering, 2019, 46(3): 180552. doi: 10.12086/oee.2019.180552
Citation: Jian Jialing, Cao Lin, Wei Xiqiao, et al. A review of photopolymers on holography volume data storage[J]. Opto-Electronic Engineering, 2019, 46(3): 180552. doi: 10.12086/oee.2019.180552

面向体全息存储技术的光致聚合物材料研究进展

  • 基金项目:
    国家自然科学基金项目(61605006);北京市自然科学基金项目(4182013)
详细信息
    作者简介:
    *通讯作者: 郭金鑫(1983-),男,博士,副教授,主要从事全息光学,高分子复合材料特性及其应用的研究。E-mail:jinxin.guo@bjut.edu.cn
  • 中图分类号: O436.3

A review of photopolymers on holography volume data storage

  • Fund Project: Supported by National Natural Science Foundation of China (61605006) and the Natural Science Foundation of Beijing (4182013), China
More Information
  • 体全息存储技术具有存储密度高、数据容量大、可并行读写、传输速度快等特点,有望解决目前大数据时代面临的数据存储成本高、存储密度小等难题。由于光致聚合物材料的体全息存储器件具有成本低,重量轻,商用价值高等优点,从上世纪90年代光致聚合物材料在体全息存储领域开始受到了广泛关注,成为体全息存储技术中最具有潜力的记录材料。本文从光致聚合物国内外研究进展出发,介绍了光致聚合物在体全息存储技术中体现出的高感光灵敏度、高衍射效率、高分辨率等优良性能。

  • Overview: In this review, recent advances in photopolymer research on volume holographic storage are introduced. Volume holographic storage technology has the advantages of high storage density, huge data capacity, parallel read and write, fast transmission speed and so on. In Big Data era, this method has great potential to meet its needs of low cost and low storage density. Photopolymer has attracted more attention because of its several advantages, such as high diffraction efficiency, extreme sensitivity and high resolution. Holographic storage devices fabricated by such materials within the advantages of low cost, light weight, and high commercial value are more suitable for marketing. Since the 1990s, photopolymer materials have received extensive attention in the field of volume holographic storage. Researchers have taken various examinations to enhance the main properties of photopolymer materials such as diffraction efficiency refractive index modulation and shrinkage rate. Changing the monomer and photoinitiator types are considered as common method to satisfy different applications. By adding chain transfer agents into the photopolymer, researchers are able to control the polymer chain length to increase crosslinking density and diminish polymerization shrinkage. An another effective way to improve refractive modulation index and reduce shrinkage rate is adding different kinds of nanoparticles(such as liquid crystal, silica nanoparticles, zirconia nanoparticles, aluminum oxide nanoparticles, gold nanoparticles and so forth) to the system. The measures currently widely taken to improve the performance of photopolymers materials are the methods described above. At present, photopolymer materials have been obtained near 100% in the diffraction efficiency, more than 10-2 in the refractive modulation index, and 0.4% in the shrinkage rate. In recent years, photopolymer materials have not only attained fruitful research results on volume holographic storage, but also have achieved good development in various optical devices, such as biosensing, fiber optic communication, etc. However, there is far from large-scale commercial production. For the long-term progress of volume holographic storage, the development of photopolymer materials with excellent performance has important scientific significance and great economic benefits. Both scientific research and commercial fields need to pay more attention to photopolymer materials.

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  • 图 1  体全息存储光学记录系统

    Figure 1.  Volume holographic storage optical recording system

    图 2  光致聚合物聚合过程。

    Figure 2.  Photopolymer polymerization.

    图 3  实验记录光路图

    Figure 3.  Experimental recording set-up

    图 4  材料收缩引起光栅变化条纹及厚度变化[11]

    Figure 4.  Grating period and thickness varietion caused by material shrinkage[11]

    图 5  北京理工大学PQ/PMMA光致聚合物记录图像(a)与其再现图(b)[24]

    Figure 5.  Image reconstruction results in polarization holography system. (a) Original transmitted image; (b) Reconstructed image[24]

    图 6  日本电气通信大学Tomita课题组用于移位多路复用全息数据存储的双光束记录光路[33]

    Figure 6.  Two-beam recording setup for shift-multiplexed HDS. SLM: Two-dimensional spatial light modulator; Pol.: Polarizer. The focal lengths of lenses 1~6 are 50 mm, 50 mm, 50 mm, 100 mm, 100 mm, and 100 mm, respectively [33]

    图 7  两步聚合反应方法示意图[37]

    Figure 7.  Schematic Illustration of holography through two-stage orthogonal Thiol−click chemistry[37]

    图 8  聚合物-纳米粒子预聚物体系光致聚合物反应示意图

    Figure 8.  Monomer-nanoparticles-polymer photopolymerization reaction process

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收稿日期:  2018-10-29
修回日期:  2019-01-21
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